For the equilibrium $A_{(g)} \rightleftharpoons B_{(g)}$,$\Delta H$ is $-40 \ kJ/mol$. If the ratio of the activation energies of the forward $(E_f)$ and reverse $(E_b)$ reactions is $\frac{2}{3}$,then:

  • A
    $E_f = 80 \ kJ/mol; E_b = 120 \ kJ/mol$
  • B
    $E_f = 60 \ kJ/mol; E_b = 100 \ kJ/mol$
  • C
    $E_f = 30 \ kJ/mol; E_b = 70 \ kJ/mol$
  • D
    $E_f = 70 \ kJ/mol; E_b = 30 \ kJ/mol$

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The $\Delta H$ value of the reaction $H_2 + Cl_2 \rightleftharpoons 2HCl$ is $-44.12 \ kcal$. If $E_1$ is the activation energy of the backward reaction and $E_2$ is the activation energy of the forward reaction,then for the above reaction:

Which one of the following is true for an exothermic reaction $A \rightleftharpoons B$, if $E_f$ and $E_b$ are the activation energies of forward and backward reactions respectively?

The rate constant of a reaction depends on

For a reaction,the activation energy $E_{a} = 0$ and the rate constant at $200 \ K$ is $1.6 \times 10^{6} \ s^{-1}$. The rate constant at $400 \ K$ will be (given $R = 8.314 \ J \ K^{-1} \ mol^{-1}$):

According to the collision theory of reaction rates:

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